CHEMISTRY CHAPTER ZERO

Physics of the Mass Spectrometer (with symbols)
CAUTION: this page contains symbols and exponents.
NOT FOR (pre high school) STUDENT CONSUMPTION

Coordinate system
x = horizontal; y = vertical. x = 0 at edge of table; y = 0 at floor
Definitions of variables

e1 = length of elastic + cradle (from point of attachment to point where handle touches the table) without tension
e2 = additional length of elastic + cradle with tension
h1 = height of table
h2 = height of attachment point of the elastic above the table
l = distance from front edge of table to point where foam atom hits the floor
mc = mass of cradle assembly
ma = mass of foam atom
theta = angle between surface of table and (elastic + cradle) just before release
v(t) = velocity of atom at time t
vx(t) = x component of velocity at time t
vy(t) = y component of velocity at time t

Assumptions

The foam atom handle touches the table at time of release.
Neglect air resistance to movement. This is a pretty good, but not perfect, assumption. [The mass spectrometer performs pretyy much as expected for foam atoms with cores. However, a piece of foam by itself is so light that the air resistance effects cause it not to travel very far -- a clear violation of this assumption.]

Calculation

KE(0) = energy stored in stretching the elastic = ½ k(e2)2 where k = the force constant of the elastic Note: we do not have to know the KE(0) in order distinguish atoms of differing weights. If one keeps e2 constant for a series of experiments, KE will be constant. The (0) refers to "time = 0". This is the time at which the elastic has reached zero tension and no longer provides additional energy to the cradle and foam atom,

KE(0) = (1/2)(ma + mc)v(0)2

NOTE: If mc >> ma, then v(0) is barely affected by the value of ma. In this case, the trajectories for foam atoms with different weights are nearly the same. This is why is is necessary to keep the weight of the cradle assembly as small as possible.

theta = arcsin(h2/(e1 + e2))

y(0) = h1 + (h2 – e1sin(theta))

x(0) = - e1cos(theta)

vy(0) = v(0)sin(theta)

vx(0) = v(0)cos(theta)

vy(t) = vy(0) – gt

vx(t) = vx(0)

y(t) = y(0) + vy(0)t – 1/2gt2

x(t) = vx(0)t
Spreadsheet
You can download a spreadsheet that does these calculatons.

 

 

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